You wouldn't "daisy-chain" them together, in any event. That would supply 24V to your system, which would quickly fry everything you turned on. If anything: You'd wire them in parallel. But you don't want to do just that.
There are several ways to add a 2nd battery. The most common way is an off/1/both/2 switch, such as this Blue Sea switch:
You would normally start your engine in "both." Then, if you were going to run equipment for long w/o the engine running (stereo while you were out at a sand-bar or whatever, maybe anchor light and VHF while out fishing at night, etc.), you'd switch to either "1" or "2" so you had a battery reserve for starting.
The trick with such a system is remembering to switch from "both" to either "1" or "2", then remembering to switch back again. Also: If you run-down, say, "1" and you try to switch to "both" to start and then charge "1", you may quickly drain "2" (it'll try to charge "1" when they're combined) and be in trouble, anyway. Otherwise you have to start and run on "2" and wait to deal with the discharged "1" when you're back at home port or whatever.
It is generally considered unwise to switch battery switches while the engine is running. Even with modern make-before-break switches. You can easily fry your alternator in a heart-beat, doing that. Some 4-position battery switches have alternator field disconnect circuits that make switching while the engine is running safer, but won't work with all alternators.
The better system, IMO, would be a combination of this Blue Sea switch:
and this Xantrex Echo Charge unit:
The concept is you have a "house bank" and a starter battery. The starter battery is used
solely for the starter motor. The "house bank" is used for everything else. The switch, when placed on "on," connects the starter battery to the starter (well, the starter relay) and the house bank to everything else. The switch does have a "combine" mode just in case. The Echo Charge distributes charging to the two (sets of) batteries, sending most to the house bank, which will usually need the most.
That's the way
I'd do it.
Jim